Россыпеобразующие алмазоносные породы и алмазы Восточной Бразилии

V. A. Petrovsky, V. I. Silaev, A. E. Sukharev, I. I. Golubeva, V. I. Rakin, V. P. Lutoev, E. A. Vasiliev

Аннотация


Совокупность геологических, геохронологических, петрографических и минералого-геохимических данных свидетельствует об участии в образовании бразильских алмазоносных конгломератов эндогенного, предположительно мантийного по происхождению, вещества. Не исключено, что алмазоносные породы из формации Сопа-Брумадиньо в Восточной Бразилии являются не вторичными (коллекторами), как это традиционно считается, а первичными источниками алмазов в современных россыпях, поиски которых ведутся здесь уже около 200 лет. Изучение бразильских, уральских и якутских алмазов подтверждает существование в природе единого бразильско-уральского типа округлых алмазов, характерных для особого флюидизатного типа коренных алмазных месторождений. По данным фотогониометрических исследований устанавливается, что кривогранная форма алмазов является результатом длительного мантийного процесса растворения, сочетающегося с механическим истиранием и химическим травлением, происходящими преимущественно в эндогенных условиях. Впервые получены количественные данные о морфологических различиях округлых алмазов в кимберлитовых и некимберлитовых месторождениях. Результаты спектроскопических исследований указывают на принципиальные особенности бразильских алмазов  – очень широкие вариации по параметрам ИК-поглощения, преобладание среди алмазов подтипа IаВ1, высокую степень агрегации структурной примеси азота и, в частности повышенную концентрацию плейтелетс, обогащение водородными центрами и центрами систем Н3 и Н4, часто преобладающими над центрами N3, повышенную (1150–1200°С) температуру и значительную длительность мантийного посткристаллизационного отжига. Вариации спектроскопических свойств свидетельствуют о кристаллизации бразильских алмазов в неустойчивой термодинамической обстановке.


Ключевые слова


Бразилия; алмазоносные горные породы; россыпи; алмазы

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Литература


Blinova G. K. 1989. Raspredelenie strukturnyh primesey v almazakh razlichnogo genezisa [Distribution of structural impurities in diamonds of different origin]. Doklady AN SSSR. 304(1):184–186. (in Russian)

Blinova G. K. 1987. Strukturnye primesi kak indikatory mekhanizma rosta prirodnykh kristallov almaza [Structural impurities as indicators of the growth mechanism of natural diamond crystals]. Doklady AN SSSR. 294(4): 868–871. (in Russian)

Voytkevich G.V., Kokin A.V., Miroshnikov A.E., Prokhorov V.G. 1990. Spravochnik po geokhimii [Handbook of Geochemistry]. Moskva, Nedra, p. 480. (in Russian)

Kaminskiy F.V. 1993. Nekotorye osobennosti mineralogii lamproitovykh tufov rayona Prezidente Olegario (shtat Minas Zherais, Braziliya) [Some features of the mineralogy of lamproite tuffs of region of Prezidente Olegario (State of Minas Gerais, Brazil)]. Mineralogicheskiy zhurnal. 15(1):3–8. (in Russian)

Klyuev Yu.A. 1971. Intensivnost polos v IK-spektre pogloshcheniya prirodnykh almazov [The intensity of the bands in the IR absorption spectrum of natural diamond]. Almazy. 6:9–12. (in Russian)

Klyuev Yu.A., Dudenkov Yu.A., Nepsha V. M. 1973. Nekotorye osobennosti usloviy obrazovaniya almazov po formam ikh rosta i raspredeleniyu primesnykh opticheski aktivnykh tsentrov [Some features of the diamond formation conditions on the forms of their growth and distribution of impurity optically active centers]. Geokhimiya. 7: 1029–1036. (in Russian)

Lukyanova L.I., Ostroumov V.R., Rybalchenko A.Ya. et al. 2011. Almazonosnye flyuidno-eksplozivnye obrazovaniya Permskogo Priuralya. [Diamantiferous fluid-explosive formations of Perm Pre-Urals] Moskva-St. Petersburg, GEOS, p. 240. (in Russian)

Lyutoev V.P., Glukhov Yu.V. 2006. Para-magnitnye azotnye tsentry v monokristallicheskikh i polikristallicheskikh raznovidnostyakh almaza [Paramagnetic nitrogen centers in monocrystalline and polycrystalline diamond varieties]. In Almazy i blagorodnye metally Timano-Uralskogo regiona. Materialy Vserossiyskogo soveshchaniya. Syktyvkar, Geoprint, pp. 90–92. (in Russian)

Petrovskiy V.A., Vasiliev E.A., Lyutoev V. P. et al. 2011. Osobennosti spektroskopii brazilskih almazov [Features spectroscopy of Brazilian diamonds]. Mineralogicheskiy zhurnal. 33(1): 63–71. (in Russian)

Petrovskiy V.A., Rakin V.I., Karfunkel I. et al. 2003. Almazy sovremennykh rossypey v basseyne reki Makaubas (Braziliya) [Diamonds of modern placers in the basin of Macaubas River (Brazil)]. Syktyvkarskiy mineralogicheskiy sbornik. 33: 13–40. (in Russian)

Petrovskiy V.A., Silaev V.I., Golubeva I.I. et al. 2010. O veroyatno endogennoy prirode mezoproterozoyskikh almazonosnykh «metakonglomeratov» v Brazilii [About probable endogenous origin of mezoproterozoic diamantiferous meta-conglomerates of Brazil]. Vestnik Instituta geologii Komi NC UrO RAN. 8: 23–32. (in Russian)

Petrovskiy V.A., Silaev V.I., Golubeva I.I. et al. 2011. Vostochnaya Braziliya: rossypeobrazuyushchie almazonosnye porody i almazy [Eastern Brazil: placer-forming diamond bearing rocks and diamonds]. In Problemy mineralogii, petrografii i metallogenii: Materialy nauchnykh chteniy pamyati P.N. Chirvinskogo. Perm State University, 14: 12–36. (in Russian)

Plotnikova S.P., Klyuev Yu.A., Parfianovich K.A. 1980. Dlinnovolnovaya fotolyuminestsentsiya prirodnyh almazov [The long wavelength photoluminescence of natural diamonds]. Mineralogicheskiy zhurnal. 2(4): 75–80. (in Russian)

Prirodnye almazy Rossii. [Natural diamonds of Russia] Moskva, Polyaron, 1997. p. 304. (in Russian)

Putintseva E.V., Polyakova E.I. 2012. Flyuidolity Severo-Vostochnogo Zaonezhya (Kareliya) [Fluidolites of North-Eastern Zaonezhye (Karelia)]. Materialy Vserossiyskoy konferentsii, posvyashchennoy 150-letiyu akademika F.Yu. Levinsona-Lessinga i 100-letiyu professora G.M. Saranchinoy. St. Peters-burg, SPbGU, T. 2, pp. 147–150. (in Russian)

Rakin V.I. 2008. Kristallomorfologiya okruglykh almazov Jakutii i Brazilii [Crystal morphology of rounded diamonds of Yakutia and Brazil]. In Mineraly i mineraloobrazovanie, struktura, raznoobrazie i evolyuciya mineralnogo mira, rol mineralov v proiskhozhdenii i razvitii zhizni, biomineralnye vzaimodeystviya. Syktyvkar, pp. 17–44. (in Russian)

Rakin V.I. 2010. Formirovanie krivolineynykh poverkhnostey kristallov almaza pri ikh rastvorenii [The formation of curved surfaces of diamond crystals during their dissolution]. Doklady RAN. 432(4): 528–532. (in Russian)

Rakin V.I., Martins M., Karfunkel I. 2005. Razvitie krivogrannykh form kristallov almaza uralskogo (brazilskogo) tipa [Development of the curve-faced forms of diamond crystals of Ural (Brazilian) type]. In Geologiya almaza – nastoyashchee i budushchee. Voronezh, Izd. Voronezhskogo un-ta. pp. 688–695. (in Russian)

Rakin V.I., Petrovskiy V.A. 2006. Osobennosti morfologii krivogrannykh form almazov [Morphological features of curve-faced diamond types]. In Almazy i blagorodnye metally Timano- Uralskogo regiona. Materialy Vserossiyskogo soveshchaniya. Syktyvkar, pp. 118–120. (in Russian)

Rybalchenko A.Ya., Rybalchenko T.M., Silaev V.I. 2011. Teoreticheskie osnovy prognozirovaniya i poiskov korennykh mestorozhdeniy almazov tuffizitovogo tipa [Theoretical basis of forecasting and exploration of primary diamond deposits of tuffizite type]. Izvestiya Komi NC UrO RAN, 1: 54–66. (in Russian)

Sobolev E.V., Samsonenko N.D., Ilyin V.E. et al. 1969. O preimushchestvennom sostoyanii azota v prirodnom almaze [About the predominant state of nitrogen in natural diamond]. Zhurnal strukturnoy khimii. 10: 552–553. (in Russian)

Sobolev E.V., Lenskaya S.V., Lisoyvan V. I. 1968. O plastinchatykh obrazovaniyakh v strukture prirodnykh almazov [About lamellar formations in the structure of natural diamonds]. Zhurnal strukturnoy khimii. 9(6): 29–33. (in Russian)

Stepanov A.S., Shatskiy V.S., Zedgenizov D.A., Sobolev N.V. 2007. Prichiny raznoobraziya morfologii i primesnogo sostava almazov iz eklogita trubki Udachnaya [The origin of diversity of morphology and impurities composition of diamonds from Udachnaya eclogite pipe]. Geologiya i geofizika. 48(9): 974–988. (in Russian)

Sukharev A.E., Lyutoev V.P. 2012. Rezultaty EPR-issledovaniya kvartsa iz mezoproterozoyskikh almazonosnykh metakonglomeratov Vostochnoy Brazilii [Results of ESR studies of quartz from Mesoproterozoic diamantiferous metakonglomerates of the Eastern Brazil]. In Mineraly: stroenie, svoystva, metody issledovaniya. Materialy IV Vserossiyskoy molodezhnoy nauchnoy konferentsii (Yekaterinburg, October 15-18 2012). Ekaterinburg, UrO RAN, pp. 236-238. (in Russian)

Tompkins L.A. 1992. Strukturnoe polozhenie kimberlitov Brazilii i ikh almazonosnost [Structural position of Brazilian kimberlites and their diamantiferous]. Geologiya i geofizika. 10: 108–117. (in Russian)

Shcherbakov Yu.G. 1976. Geokhimicheskaya evolyutsiya i rudnye formatsii [Geochemical evolution and ore formations]. In Problemy endogennogo rudoobrazovaniya i metallogenii. Novosibirsk, Nauka, pp. 217–229. (in Russian)

Alkmim F.F., Marshak S., Pedrosa-Soares A. S. et al. 2006. Kinematic evolution of the AraÇuai-West Congo orogen in Brazil and Africa: nutcracker tectonics during the Neoproterozoic assembly of Gondwana. Precambrian Research. 149: 43–64. doi: 10.1016/ j.precamres.2006.06.007

Alvarenga C. J. S. 1982. Comportanmento estratigraficoda formaÇao Sopa-Brmadinhono distrito diamantifero de ExtraÇao (Diamantina). Congr. Bras. De Geologia. Salvador, Anais. 1: 168–176.

Babinski M., Pedrosa-Soares A.S., Trindade R.I.F. et al. 2012. Neoproterozoic glacial deposits from the AraÇuai orogen, Brazil: Age, provenance and correlations with the São Francisco craton and West Congo belt. Gondwana Research. 21: 451–465. doi: 10.1016/j.gr. 2011.04.008

Boyd S. R., Kiflawi I., Woods G.S. 1994. The relationship between infrared absorption and the A defect concentration in diamond. Phil. Mag., Part B. 69(6): 1149–1153. doi: 10.1080/ 01418639408240185

Boyd S. R., Kiflawi I., Woods G.S. 1995. Infrared absorption by the B nitrogen aggregate in diamond. Phil. Mag., Part B. 72(3): 351–361. doi: 10.1080/13642819508239089

Chaves M. L. S. C. 1997. Geologia e mineralogia do diomanteda Serra do Espinenhacoem Minas Gerais. PhD Thesis: Universidade de Sao Paulo. p. 289.

Chaves M. L. S. C. , Dussin T. M. , Sano Y. 2000. The Source of the Espinhago Diamonds: Evidences from SHRIMP U-Pb zircon ages of Sopa Conglomerate and Pb-Pb zircon evaration ages of metavolcanic rocks. Revista Brasileira de Geociencias. 30(2): 265–269.

Chaves M. L. S. C., Karfunkel J. 1997. A protobacia do Rio Jeguitinhonha durante o Cretaceo Inferior e seu potencialdiamanifero. Geociencias. 16: 191–203.

Chaves M. L. S. C. , Karfunkel J. , Svisero D.P. 1998. Sobre a polemica da origin do diomante na Serra do Espinhaco (Minas Gerais): um enfogue mineralogico. Revista Brasileira de Geociencias. 28(3): 285–294.

Chaves A. O. 2005. Nitrogen centres and mineral inclusions of diamonds from Minas Gerais (Brasil) as revealed by vibrational spectroscopy. Proc. of the II South American Symposium on diamond geology. pp. 43–48.

Chemale Ir. F., Dussin I.A., Alkmin F.F., Martins M.S., Queiroga G., Armstrong R., Santos M.N. 2011. Unravelling a Proterozoic basin history througen detrital zircon geochronology: The case of the EspinhaÇo Supergroup, Minas Gerais, Brazil. Gondwana Research. 22(1): 200-206. doi:1016/j.gr. 2011.08.016

Сloos H. 1941. Bau und Tatigkeit von Tuffschoten. Geologishe Rundschau. 32: 708–800.

Dussin I.A., Dussin T.M. 1995. Supergrupo EspinhaÇo: Modelo de EvoluÇao Geodinamica. Geonomos. 1: 19–26.

Gonzaga G.M., Tompkins L.A. 1991. Principais depositos minerais do Brazil. Gemas e rochas ornamentais. DNPM-CPRM. 4-A: 53–116.

Hettich M.A. 1977. Glaciacao proterozoica no centronorte de Minas Gerais. Rev. Bras. Geociecias. 7: 87–101.

Hayman P., Kopylova M., Kaminsky F.V. 2003. Alluvial diamonds from the Rio Soriso (Juina, Brasil). Ext. abstr. 8 Int. Kimberlite Conference. P. art FLA_0320.

Junior F.C., Dussin I.A., Martins M.S. et al. 2010. The Espinhaco Supergroup in Minas Gerais: a Stenian Basin? VII SSAGI South American Symposium on Isotope Geology Brasilia. pp. 552–555.

Kaiser W., Bond W. 1959. Nitrogen, a major impurity in common type I diamond. Phys. Rev. 115:857. doi: 10.1103/PhysRev.115.857

Kaminsky F.V., Khachatryan G.K. 2001. Characteristics of nitrogen and other impurities in diamond as revealed by infrared absorption data. Canadian Mineralogist. 39(6):1733–1745. doi: 10.2113/gscanmin. 39.6.1733

Kaminsky F.V., Sablukov S.M., Sablukova L.I., Zakharchenko O.D. 2009. The Fazenda Largo off-craton kimberlites of Piaui State, Brazil. Journal of South American Earth Sciences. 28(3): 288–303. doi: 10.1016/j. jsames.2009.06.003

Karfunkel J., Chaves M. L. S. C. 1995. Conglomerados Cretacicos da Serra do Cabral, Minas Gerais: Um modelo para a redistribuicao coluvio-aluvionar dos diamantes do Medio Sao Francisco. Geociencias. 14:59–72.

Karfunkel J., Hoppe A. 1988. Proterozoic glaciations in central-eastern Brazil: synthesis and model. Paleaeogeography, Paleoclimatology, Paleoecology. 65:1–21.

Karfunkel J., Martins M., Scholz R. et al. 2001. Diamonds from the Macaubas river basin (MG. Brazil): characteristics and possible source. Revista Brasileira de Geociencias. 31:445–456.

Lister G.S., Etheridge M.A., Symonds P.A. 1991. Detachment models for the formation of passive continental margins. Tectonics. 10(5): 1038–1064. doi: 10.1029/90TC01007

Martins M.S. 2006. Geologia dos diamantes e carbonados do Rio Makaubas (MG). PhD Thesis: Universidade Federal de Minas Gerais. p. 246.

Martins-Neto M.A. 2000. Tectonics and sedimentation in a paleo/mesoprpterozoic rift-sag basin (EspinhaÇo basin, southeastern Brazil). Precambrian Research. 103(3-4):147–173. doi: 10.1016/S0301-9268(00) 00080-2

Martis-Neto M.A. 2007. Sequence stratigraphic framework of Proterozoic successions in eastern Brazil. Marine and Petroleum Geology. 26(2):163-176. doi: 10.1016/j. marpelgeo.2007.10.001.

Martins-Neto M.A., Hercos C.M. 2002. Sedimentation and tectonic seting of Early Neoproterozoic glacial deposits in south-eastern Brazil. In Precambrian Sedimentary Environments: A Modern Approach to Ancient Depositional System. (Eds W. Altermann and P. L. Corcoran), Blackwell Publishing Ltd., Oxford, UK. doi: 10.1002/9781444304312. ch18

McCandless T.E., Waldman M.A., Gurney J.J. 1994. Macrodiamonds and microdiamonds from Murfreesboro Lamproites, Arkansas: morphology, mineral inclusions and carbon isotope geochemistry. In International Kimberlite Conference - Diamonds: Characterization, Genesis and Exploration, At Araxa, Brasilia, Vol. 2, pp.78–97.

Moraes L.J. 1932. Area ocupada pela Formacao Macaubas no norte de Minas Gerais. Ann. Acad. Bras. Sci. 4:111–114.

Rakin V.I. 2011. Curved Surfaces upon Dissolution As a Manifestation of Physicochemical Properties of Crystal Structure. Crystallography Reports. 56(2):289–297. doi: 10.1134/S1063774511020155

Reynolds D.L. 1954. Fluidization as a geological process and its bearing on the problem of intrusive granites. Am. J. of Sci. 252(10): 577–614.

Robinson D.N. 1979. Surface textures and other features of diamonds. Ph.D. Thesis, University of Cape Town/South Africa. p. 221.

Robinson D.N., Scott J.A., Van Niekerk A., Anderson V.G. 1989. The seguence of events reflected in the diamonds of some southern African kimberlites. Geol. Soc. Australia. Sp. Publ. 14:990–1000.

Sutherland D.G. 1982. Type transport and sorting of diamonds by fluvial and marine processes. Econ. Geol. 77(7):1613–1620. doi: 0.2113/gsecongeo.77.7.1613

Svisero D.P. 1995. Distribution and origin of diamonds in Brazil: an overview. J. Geodinamics. 20(4):493–514. doi: 10.1016/0264-3707(95)00017-4

Taylor W.R., Jaques A.L., Ridd M. 1990. Nitrogen-defect aggregation characneristics of some Australasian diamonds: Time-temperature constraints on the source regions of pipe and alluvial diamonds. Am. Miner. 75:1290–1310.

Uhlein A., Trompette R.R. , Egudio-Silva M. 1998. Proterozoic rifting and closure, SE border of the São Francisco Craton, Brazil. Journal of South American Earth Sciences. 11(2):191–203. doi: 10.1016/S0895-9811(98) 00010-8

Vance E.R., Harris J.W., Milledge H.J. 1973. Possible origins of a-damage in diamonds from kimberlite and alluvial sources. Mineral. Mag. 39:349–360.

Woods G.S. 1986. Platelets and the infra-red absorption of type Ia diamonds. Procceding of the Royal Society London, A407:219–238.




DOI: http://dx.doi.org/10.17072/psu.geol.30.33

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